Chemical failure modes of AlQ3-based OLEDs: AlQ3 hydrolysis

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Chemical failure modes of AlQ3-based OLEDs: AlQ3 hydrolysis.

Tris(8-hydroxyquinoline)aluminum(III), AlQ3, is used in organic light-emitting diodes (OLEDs) as an electron-transport material and emitting layer. The reaction of AlQ3 with trace H2O has been implicated as a major failure pathway for AlQ3-based OLEDs. Hybrid density functional calculations have been carried out to characterize the hydrolysis of AlQ3. The thermochemical and atomistic details fo...

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ژورنال

عنوان ژورنال: Physical Chemistry Chemical Physics

سال: 2006

ISSN: 1463-9076,1463-9084

DOI: 10.1039/b514898g